Bis{(E)-2,4-diiodo-6-[(2-morpholinoethyl)iminomethyl]phenolato}nickel(II)
نویسندگان
چکیده
In the title mononuclear nickel(II) complex, [Ni(C(13)H(15)I(2)N(2)O(2))(2)], the Ni(II) atom is four-coordinated in a tetra-hedral geometry by the imine N and phenolate O atoms of the two Schiff base ligands. The O and N atoms of the morpholine substituent in the ligand are not involved in coordination to the Ni atom.
منابع مشابه
Redetermination of bis(2-formylphenolato-κ2 O,O′)nickel(II) as bis[2-(iminomethyl)phenolato-κ2 N,O′]nickel(II)
The crystal structure of bis-(2-formyl-phenolato-κ(2)O,O')nickel(II), [Ni(C(7)H(5)O(2))(2)], a square-planar centrosymmetric complex, has been reported previously [Li & Chen (2006). Acta Cryst. E62, m1038-m1039]. However, a number of warning signs allows the assumption that the carbonyl group in the salicylaldehydate ligand of the claimed complex is incorrect. The crystal structure was therefor...
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